Modern refrigerants have been developed to be more environmentally safe than many of the early chlorofluorocarbon-based refrigerants used in the early- and mid-twentieth century. These include HCFCs (R-22, as used in most U.S. homes before 2011) and HFCs (R-134a, used in most cars) have replaced most CFC use. HCFCs, in turn, are supposed to have been in the process of being phased out under the Montreal Protocol and replaced by HFCs such as R-410A, which lack chlorine. HFCs, however, contribute to climate change problems. Moreover, policy and political influence by corporate executives resisted change. Corporations insisted that no alternatives to HFCs existed. The environmental organization Greenpeace provided funding to a former East German refrigerator company to research an alternative ozone- and climate-safe refrigerant in 1992. The company developed a hydrocarbon mix of isopentane and isobutane, but as a condition of the contract with Greenpeace could not patent the technology, which led to its widespread adoption by other firms. Their activist marketing first in Germany led to companies like Whirlpool, Bosch, and later LG and others to incorporate the technology throughout Europe, then Asia, although the corporate executives resisted in Latin America, so that it arrived in Argentina produced by a domestic firm in 2003, and then finally with giant Bosch's production in Brazil by 2004.
The amount of time air duct cleaning takes can depend on how extensive your duct system is, how old your air ducts are, and whether they have ever been cleaned. On average, expect a standard size home (between 2,000 and 3,000 square feet) to take 2-5 hours for one to two technicians to clean. Here are the proper protocol and equipment you should expect from a professional duct cleaning service, as recommended by the Environmental Protection Agency:
Dichlorodifluoromethane (R-12) was the most common blend used in automobiles in the U.S. until 1994, when most designs changed to R-134A due to the ozone-depleting potential of R-12. R-11 and R-12 are no longer manufactured in the U.S. for this type of application, so the only source for air-conditioning repair purposes is the cleaned and purified gas recovered from other air conditioner systems. Several non-ozone-depleting refrigerants have been developed as alternatives, including R-410A. It was first commercially used by Carrier Corp. under the brand name Puron.
Free cooling systems can have very high efficiencies, and are sometimes combined with seasonal thermal energy storage so that the cold of winter can be used for summer air conditioning. Common storage mediums are deep aquifers or a natural underground rock mass accessed via a cluster of small-diameter, heat-exchanger-equipped boreholes. Some systems with small storages are hybrids, using free cooling early in the cooling season, and later employing a heat pump to chill the circulation coming from the storage. The heat pump is added-in because the storage acts as a heat sink when the system is in cooling (as opposed to charging) mode, causing the temperature to gradually increase during the cooling season.